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- 要約等Details recent scientific advances in the field of carbon materials and carbon nanomaterials including: polymers, c......rbon nanocomposites, and graphene; Covers a wide spectrum of topics related to carbon science, from organic chemistry to devices, physical chemistry, applied physics, synthesis, and device implementation; Describes experimental and theoretical approaches in several categories of carbon-related materials. This book summarizes the recent advances in carbon-related materials. It covers both experimental and theoretical approaches in graphene and ......anocarbon materials, carbon composites and thin films, organic sy...
- 内容細目...ctroscopy; 2.2 Infrared Spectro......copy; 2.4 Rayleigh Imaging; 2.5 Photoluminescence; 2.6 Ultrafast Optics; 3 Properties; 3.1 Thermal Properties; 3.1.1 Raman......oscopy; 3.2 Doping; 3.2.1 Absor...... 3.2.2 Fast Optics; 3.3 Strain; 3.3.1 Infrared Spectroscopy; 3.4 Thickness and Stacking; 3.5 Defectiveness; 3.5.1 Infrared Spectro...... 3.5.2 Photoluminescence; 3.6 Electronic Structure; 3....... 3.6.2 Photoluminescence; 3.6.3 Infrared Spectro......4 Ultrafast Optics 3.7 Distinction of Effects and Combination of Techniques4 Conclusion; References; Submerged Liquid Plasma for the Formation of Nanostruc......ured Carbon; 1 Introduction; 2 Formation of Na...
- 件名Nanostructured materials. Carbon. TECHNOLOGY & ENGINEERING--Engineering (General) TECHNOLOGY & ENGINEERING--Reference.
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- 要約等The formation of graphite intercalation compounds (GICs) in aqueous solutions has attracted much attention, but reversibility in the formation/deformation of GICs is a challenging issue to construct highly safe rechargeable batteries. In this study, we use......operando analysis (X-ray diffraction and Raman sp......ctroscopy) to discuss the feasibility of using fluoride-containing polyatomic anions in the formation of GICs in aqueous highly concentrated solutions. We found that the intercalation of anions containing a C₂F₅ moiety (such as [N......does not occur in the bulk of graphite, but only in the surface region. In addit...
- 件名General Materials Science Chemistry (miscellaneous)
- 参照Electrochemical In Situ/<i>operando</i> Spectroscopy and Microscopy Part 2: Battery Applications
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- 参照Momentum shift of Dirac cones in the silicene-intercalated com......><mml:mtext>CaSi</mml:mtext><mm......ml:math> Reversible Formation of Ammonium Persulfate/Sulfuric Acid Graphite Intercalation Compounds and Their Peculiar Raman Spectra Temperature-Induced Plasmons in a Graphite Sheet. 低次元電子系の......次摂動の効果 Observation of Dislocation Behavior in Graphite by Using Ultrasonic Atomic Force Microscopy.
- 並列タイトル等（連結）Structure and Dynamics
- 並列タイトル等Structure and Dynamics
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- 要約等High resolution <SUP>13</SUP...... been observed in highly oriented crystals of pristine graphite and K-GIC’s. The NMR spectrum consists of several well resolved lines which can be assigned to the interior and bounding carbon layer......UP>13</SUP>C spin-lattice relaxation time <I>T</I><SUB>1</SUB> shows the metallic characteristics, <I>T</I><SUB>1</SUB><I>T</I>=constant betw......and R.T. From <I>T</I><SUB>1</SUB> o......esolved absorption line, the c-axis charge distribution was quantitatively determined for stage 3 and 6, which is strongly inhomogeneous. The obtained distribution was also sup......ed by an analysis of the frequency shift of <S...
- 参照<sup>13</sup>C-NMR Shift of Highly Concentrated Metallic and Semiconducting Single-Walled Car......otubes Electronic States and Superconductivity in Alkali-Intercalated Fullerides:<sup>13</sup>C-NMR Study in Na<sub>2</sub......A New Self-Consistent Band Stru......8K The Electronic States of the......Hydrogen-Potassium-Graphite Ternary Intercalation Compounds C<sub>8</sub>KH<sub><i>x</i></sub>(<i>x</i>=0.5, 1.0) Self-Consistent Band Structures of First-Stage Alkali-Metal Graphite Intercalation Compounds Electronic State and Arr......Hydrogen Atoms in Ternary Graphite Intercalation Compounds C<sub>8</sub>K....../sup>C NMR Studies
- 参照Observation of high-resolution 13C n.m.r. spectra in highly oriented pyrolitic graphite (HOPG) Electrostatic interactions and staging in graphite intercalation compounds Raman scattering from intercalated donor compounds of graphite Long-Range Elastic Interactions and Staging in Graphite Intercalation Compounds Theoretical Interpretation of Carbon-13 Hyperfine Interactions in Electron Spin Resonance Spe......tra Absolute spin susceptibility of K-graphite intercalation compounds and C24SbCl5: Orbital paramagnetism Band structu......and electrostatic effects in third and fourth stages of graphite acceptor compounds Prediction...
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- 要約等...ccessfully applied to KC<SUB>8<......sC<SUB>8</SUB> in 1982, we have......he superconducting transition temperature <I>T</I><SUB>c</SUB> f......UB>6</SUB> to find that the sam...... the observed <I>T</I><SUB>c</SUB> in those compounds as well, indicating that it is a unified model for superconductivity in the graphite intercalation compounds with <I>T</I><SUB>c</SUB> ranging over three orders of magnitude. Further enhancement of <I>T</I><SUB>c</SUB> w......ll beyond 10 K is also predicted.
- 件名first-principles transition temperature polar coupling phonon mechanism superconductivity graphite intercalation compounds
- 著者標目Takada Yasutami
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- 件名Clathrate compounds Graphite
- 件名（識別子）Clathrate compounds Graphite
- 一般注記Includes bibliographical references Includes indexes
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- 要約等The effect of cooling rate on the ......phen (dHvA) oscillation and on the in-plane structu......e has been studied by the use of electron diffraction in the second st......Cl<SUB>5</SUB>-graphite intercalation compounds (GIC’s). When the cooling rate through......the phase transition temperature, 210 K, is fast, a large......R16° corresponding to the higher temperature phase remains, while non-negligible volume of the diffuse diffraction pattern of the intercalant corresponding to the low t......ars. Compared with the case of the slow cooling through 210 K, the amplitudes of the dHvA oscillation were found to increase with...
- 件名General Physics and Astronomy
- 参照...Cl<SUB>5</SUB>-Graphite Intercalation Compounds. II Induced Torque of SbCl5-Graphite Intercalation Compounds Magnetic Susceptibility of SbCl5-Graphite Intercalation Compounds
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- 要約等The effect of cooling rate on the ......phen (dHvA) oscillation and on the in-plane structu......e has been studied by the use of electron diffraction in the second st......Cl<SUB>5</SUB>-graphite intercalation compounds (GIC’s). When the cooling rate through......the phase transition temperature, 210 K, is fast, a large......R16° corresponding to the higher temperature phase remains, while non-negligible volume of the diffuse diffraction pattern of the intercalant corresponding to the low t......ars. Compared with the case of the slow cooling through 210 K, the amplitudes of the dHvA oscillation were found to increase with...
- 著者標目Yosida Yositaka Tanuma Sei-ichi
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- 要約等We investigate the electronic structure of ......Cl<SUB>3</SUB> graphite intercalation compounds by means of discrete variational (DV)-Xα molecular orbital calculation and ultraviolet photoelect...... DV-Xα calculation of the Au<SU......Cl<SUB>6</SUB> intercalate reveals the importance of relativistic effect due to......atoms. The terminal Cl 3p orbital contributes mainly to the lowest unoccupied molecular orbital (LUMO) of A....../SUB> molecule in addition to the minor contribution of the Au 5d......t. The calculation of (Au<SUB>2......>-0.5</SUP>, which is considered to be intercalate species realized in graphitic galleries thr...
- 件名graphite intercalation compounds (GICs) discrete variational (DV)-Xα molecular orbital calculation ultraviolet photoelectron spectroscop...
- 参照Insertion du chlore dans le graphite X-ray absorption spectroscopy and X-ray diffraction of AuCl3-graphite Band structure......model and dynamical dielectric function in lowest stages of graphite acceptor compounds Observations macroscopiques et microscopiques des produits d'insertion du graphite avec le trichlorure d'or Electronic and geometric structures of....../Math/MathML" display="inline"><mml:mrow><......mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mm....../Math/MathML" display="inline"><mml:mrow><......mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mm......ow></mml:math> Intercalation compounds of graphite Computa...
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- 要約等...al-plane electrical resistivity was studied for C_8K, C_......s and C_<24>Cs intercalation compounds. The admission of hydrogen ......8K and C_<24>K induced a reversible change in the resistivity below 200 K, and an irreversible increase in the resistivity at room temperature.
- 著者標目SANO Mizuka INOKUCHI Hiroo
- 出版者（掲載誌）Tohoku University
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- 要約等Theory of the <I>c</I>-axis conduction in graphite intercalation compounds was proposed by Sugihara and by Shimamura. Though two theories apparently seem to be different, the underlying physics is the same. In this article the previous treatments are largely revised and extende......count for a maximum of ρ<SUB>c</SUB> vs <I>T</I> curve observed in some low stage compounds, a new mechanism is introduced and a......ment on the semiconductor-like <I>T</I>-dependence of ρ<SUB>c</SUB> in high stage GICs, is presented. An expression of the <I>c</I>-axis thermoelectric power is derived in connection with ρ<SUB>c</SUB> in the low st...
- 件名graphite intercalation compounds thermoelectric power <I>c</I>-axis conduction
- 著者標目Sugihara Ko
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- 参照<i><i>C</i></i>-Axis Thermoelectric Power of Stage-2 Graphite Intercalation Compound with Iodine Monobromide
- 著者標目Toshiaki Enoki Noriaki Sakamoto Keisuke Nakazawa Kazuya Suzuki Ko Sugihara Koji Kobayashi
- 出版者（掲載誌）American Physical Society (APS)
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- 要約等The <I>c</I>-axis resistivity ρ<SUB>c</SUB> which indicates a metallic temperature d......e was measured in stage 1 and 2 potassium-hydrogen-graphite intercalation compounds (KH-GICs) in the temperatu......suggests a hopping conduction process for the <I>c</I>-axis transport mechanism, which is governed by t......mber of conduction paths and the transfer integral across the intercalate layer. The magnitudes of ρ<SUB>c</SUB> in stage 1 and stage 2 compounds are mainly dominated by the number of their impurity and defects concentrations in the conduction paths.
- 件名...t property hopping conduction graphite intercalation compound
- 著者標目Nakazawa Keisuke Suzuki Kazuya Enoki Toshiaki Sugihara Ko Mizuno Seiji
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- 参照...endence of C-Axis Resistivity in Potassium-Hydrogen-Graphite Intercalation Compounds Theory of the c-Axis Conduction and Thermoelectric Power in Graphite Intercalation Compounds Theory of the<i><i>a</i></i>- and<i><i>c</i></i>-Axis Resistivity and Magnetoresistance in MoCl<sub><b>5</b></sub>Graphite Intercalation Compounds
- 著者標目Ko Sugihara
- 出版者（掲載誌）American Physical Society (APS)
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- 一般注記"Principal symposium support, NASA Lewis Research Cent......my Research Office, industrial support, Gen...... Laboratory, Union Carbide Corporation Parma Technical Center." Includes bibliographical references and index.
- 著者標目Materials Research Society. Fall Meeting (1984 : Boston, Mass.) Eklu...
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- 参照Theory of the c-Axis Conduction and Thermoelectric Power in Graphite Intercalation Compounds Dimensional Crossover ......dent Magnetoresistance of Magnetic Graphite Intercalation Compounds; MCl<sub><b>2</b></sub>GIC's (M=Cu and C...... Theory of the<i><i>a</i></i>- and<i><i>c</i></i>-Axis Resistivity and Magnetoresistance in MoCl<sub><b>5</b></sub>Graphite Intercalation Compounds
- 著者標目R. Powers A. K. Ibrahim G. O. Zimmerman M. Tahar
- 出版者（掲載誌）American Physical Society (APS)
<I>C</I>-Axis Conduction in Low Stage Graphite Intercalation Compounds with Iodine Monochrolide 55 7
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- 要約等The intrinsic electrical resistivities in <I>c</I>-direction (ρ<I><SUB>c</SUB></I>) of stages-1 and -2 graphite intercalation compounds (GIC) with ICl have been su......essfully determined. The temper......ure dependence is qualitatively metallic-like, and does no......hermal hysteresis so far considered to be characteristic of acceptor-type GICs. Dominant carriers are positive holes not le......</SUP>. The mobility values where......o low to deal with the matter on the basis of the band model. An interpretation has been given by Sugihara’s “impurity-assisted hopping mechanism” which however is modified so as to take into ...
- 著者標目Ohta Yasumitsu Kawamura Kiyoshi Tsuzuku Takuro
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- 参照Anisotropies in the Magnetotransport Properties of Quasi-Two-Dimensional<i>η</i>-Mo<sub><b>4</...... Theory of the<i><i>a</i></i>- and<i><i>c</i></i>-Axis Resistivity and Magnetoresistance in MoCl<sub><b>5</b></sub>Graphite Intercalation Compounds
- 著者標目Masatsugu Suzuki Chaoli Lee Itsuko S. Suzuki Keiko Matsubara Ko Sugihara
- 出版者（掲載誌）American Physical Society (APS)
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- 要約等Based on Blinowski-Rigaux’s band model, an expression for the <I>g</I>-shift (<I>Δg</I>) in stage-4 donor graphite intercalation compound has been derived by using the Dresselh......-Dresselhaus spin-orbit Hamiltonian. If the bands are...... A<SUP>+</SUP> in order of energy <I>E<SUB>s</SUB></I>, <I>g</I>-shifts for A<SUP>±......es are of opposite sign to each other, and in most cases |<I>Δg</I>(A<SUP>−</SUP>)|>|<I>Δg</I>(B<SUP>−</SUP>)|>|<I>Δg</I>(B<SUP>+</SUP>)|>|<I>Δg</I>(A<SUP>+</SUP>)|. Since the higher the energy <I>E<SUB>s</SUB></I> the less the state density, the total <I>g</I>-shift <I>Δg</I>=Σ<I><SUB>s</SUB></I>Σ<...
- 著者標目Sugihara Ko Matsubara Keiko Tsuzuku Takuro
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- 参照Specific Heats of Graphite-Iodine Monochloride Intercalation Compounds Temperature an......endence of C-Axis Resistivity in Potassium-Hydrogen-Graphite Intercalation Compounds <i>c</i>-Axis Compressibility and Thermal Expansion of Gold Trichloride-Graphite Intercalation Compounds (AuCl<sub>3</sub>-GICs) The Electronic States of the......Hydrogen-Potassium-Graphite Ternary Intercalation Compounds C<sub>8</sub>KH<sub><i>x</i></sub>(<i>x</i>=0.5, 1.0) Electronic State and Arr......Hydrogen Atoms in Ternary Graphite Intercalation Compounds C<sub>8</sub>K....../sup>C NMR Studies
- 著者標目Toshiaki Enoki Mizuka Sano Hiroo Inokuchi
- 出版者（掲載誌）American Physical Society (APS)